![]() Van der Waals forces Van der Waals forces account for the attraction of the shifting electron-rich portion of one molecule to the shifting electron-poor portion of another molecule (temporary states of electronegativity, e.g. shows how the structure and composition of various solids determine their properties, including conductivity, solubility, density, and melting point.Melting point was determined in open-glass capillaries on a Gallenkamp melting point apparatus. Dipole-Dipole A dipole force occurs when the positive end of a polar molecule is attracted to the negative end of another polar molecule (CH 3COCH 3, propanone). The crystal structure of substituted purine derivative.When hydrogen is bonded to fluorine, the bond is very strong, when bonded with chlorine it has moderate strength, and when bonded with another hydrogen, the molecule is non-polar and is very weak. Not all hydrogen bonds have the same strength, it depends on the electronegativity of the atom it is bonded to. This next diagrams summarizes the physical states of the first six alkanes. Caffeine is generally less soluble in organic solvents than in hot water. The boiling points for the 'straight chain' isomers and isoalkanes isomers are shown to demonstrate that branching decreases the surfaces area, weakens the IMFs, and lowers the boiling point. ![]() It is very soluble in hot water upon cooling, the solution deposits crystals of caffeine monohydrate. This represents a polar covalent bond in which the electrons are shared unequally. Pure caffeine (trimethylxanthine) occurs as a white powder or as silky needles, which melt at 238 C (460 F) it sublimes at 178 C (352 F) at atmospheric pressure. The electron cloud around the fluorine atom is large and has high electronegativity while the electron cloud around the hydrogen atom is small and has much less electronegativity. Hydrogen bond A hydrogen atom that is bonded to another atom by sharing its valent electron has low electronegativity (e.g. Caffeine is a soft, white crystal or powder with an intensely bitter taste when in its pure form.It is this neutrality that makes the ionic bond so strong, and why it would take more energy to break that bond than a different type of bond. Physical Properties of Caffeine Melting Point of Caffeine, 235 C Boiling Point of Caffeine, 178 C Density, 1.23 g/cm Molar Mass, 194.19 g/mol Solubility. It is made up of eight carbons, ten hydrogens, four nitrogens, and two. In the example of NaCl, the positively-charged sodium ion is held in close proximity to the negatively-charged chloride ion and the net effect is a molecule that is electrically neutral. 39K views Chemical Composition of Caffeine The compound caffeine comprises carbon, nitrogen, hydrogen, and oxygen atoms. Ionic bond Ionic bonding involves an electron being donated from one atom to another (e.g.
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![]() In the unit field of the calculator, choose the units you are currently using from the drop-down menu. In the length field on the calculator, enter the length of the item you are measuring. This calculator is perfect for household tasks, translating measurements, elementary school math, and much more. Just enter the length of whatever you need to measure, choose the measurement you are currently using, pick how specific you need your calculations to be and the calculator will do the rest. The car weighs 1850 kg and increases its speed from 27 to 81 km/h.If you need to convert inches to feet, centimeters to miles or meters to picometers, our completely free length conversion calculator can help! It’s fast, simple and just as exact as you need it to be. the division harvested 1250 kg, the 2nd division by a fifth more than the 1st division and the 3rd division by a sixth more than the second division. Three divisions of nature protectors participated in the collection of chestnut trees.1. How many grams of nitrogen per 1 m² if we bought a 25 kg package and thereby evenly fertilized a garden of 12 a? Nitric lime contains an average of 19% nitrogen and 55% calcium oxide. Calculate belt width if one dm³ copper weighs 8.9 kg. How many tons of sugar beet can be obtained from three tons of sugar?įrom the 1600 mm long sheet of copper plate 2 mm thickness, we have separated over the whole length of the belt weighing 6000 g. Calculate how many times more earns clever 25-year-old mġ50 kg of sugar beet yields 24 kg of sugar. In Slovakia/Czech Republic, many people study political science, mass media communication, social work, and many management MBAs. You'll notice that the college is up slowly every other high school. How many CZK cost one kilogram of chicken meat so that the price of one kilogram of meat of two colors One kilogram of pork is 40 CZK more expensive than a kilogram of chicken. ![]() One kilogram of meat of two colors is 650 g of pork, and the rest is chicken. What is the weight of the stone needed to build this pyramid if the weight of 1 m³ of stone is 2.5 t? The base edge is 227 m long, and the pyramid is 140 m high. The Great Pyramid of Giza has the shape of a regular quadrangular pyramid. How much does an empty aquarium weigh with dimensions: length = 40 cm, width = 30 cm, height = 20 cm, if 1 dm² of glass weighs 300 g? Calculate its weight in kilograms. Please round the result to 3 decimal places. How much silver did they use onĬalculate the total energy of a body performing a harmonic oscillating motion if its mass is 200 g, the deflection amplitude is 2 cm, and the frequency is 5 Hz. The tray they brought breakfast to the landlord's bed is made of an alloy that contains 830 ‰ of silver. Calculate 1.5 ‰ from 4.5 liters of blood. How many grams should we look for on the package of sand? (1 kilogram= 1,000 grams) A. When we went to the store, the bags of sand only stated the number of grams on the package. Determine the frequency of the natural oscillation of the resulting oscillator. What amount of alcohol did the driver have in the blood?Ī weight of 1 kg was suspended from the spring, and the spring was extended by 1.5 cm. About 5 kg of blood circulates in the human body. How many kilograms does one freight car weigh?Īfter a traffic accident, police measured 1.16 permille of alcohol in the driver's blood. The weight of the locomotive and all wagons is 1009000 kg. Twenty-five identical freight wagons are connected behind the locomotive. Conversion of a mass unit in word math problems and questions ![]() Decks which won’t have a way to kill if they don’t know it is coming, against Bogles or Spirits they do have Path in main but have a typical tend to trim them down as they think Snapcaster is the only target. ![]() Typical matchups that I have put this in against are Elves, Dredge, Grixis Death Shadow, Eldrazi Aggro, Zoo, Burn, Huamns, Spirits and Bogles. We want to be putting this combo in vs agro decks or combo decks. The Way Madcap Experiment is worded we have to do it all in order of the card to resolve the complete spell. We put other 20 cards to the bottom of the library in a random order. We then count up the cards which have been revealed so 21 and we take 21 but our life total can’t change now as Platinum Emperion is on the battlefield. We have revealed 20 card before we hit Platinum Emperion and we place it onto the battlefield meaning now our life total can’t change. Only having Platinum Emperion as the only artifact we can hit means that we won’t die no matter how many cards we begin to reveal. You have just cast Madcap Experiment to find your Platinum Emperion. This sideboard combo came after I kept losing to burn / aggro decks all the time and I needed a way to stop them. The most recent add to these decks which I have been using in the sideboard is Madcap Experiment with Platinum Emperion which is very useful against fast agro and decks won’t be able to deal with an 8/8 which says ” Your Life Total Can’t Change”. The deck I play in Modern is Breach Moon / Blue Moon and similar controlling Blue / Red decks. ![]() "In 2018 we are still just at the beginning of people socializing online, which makes it an exciting time to be part of the evolution of IMVU. ![]() "In a game, someone else creates the character story but in IMVU, you create your own story," Bigelow says. Bigelow, who recently joined IMVU from a neuroscience startup, thinks people who describe IMVU as a mere role-playing game are missing the point. When I high-five someone in IMVU, I feel it," says Tsui of his earliest IMVU experiences.Īt the helm of IMVU's social experience is Lauren Bigelow, chief of product. ![]() It felt so real that I unconsciously began projecting myself onto my avatar feeling the psychological exhilaration as if in real-life. In addition to chatting, I was able to experience nonverbal cues such as gestures, proximity, and expressions. "I vividly recall my first time sitting on a virtual sofa interacting with another avatar. Compared to real life, an avatar allows a greater ability to optimize how you present yourself in a social setting, which often makes an avatar a better communicator than you in the real world. Through gestures, movement, and interactions with others, IMVU avatars create a greater sensation of social presence - the feeling of being with someone else in a digital environment. On IMVU, your avatar, customized to your preferences, represents you. People love to interact with others in digital spaces, according to virtual reality and digital human expert Jeremy Bailenson, founder of the Virtual Human Interaction Lab at Stanford University. At IMVU, we are spreading the power of friendships through our product's experience to address the rising rates of loneliness in all generations." As CEO Daren Tsui explains, "Virtual worlds will be the next generation social platform connecting people in a way that exceeds both face-to-face connection and the curated feeds of Facebook and Instagram. That social aspect of the online experience is exactly the focus of IMVU. Instead of posting past each other on Facebook or Instagram, IMVU user interactions are hyperpersonal - the experience is similar to the fidelity of face-to-face interaction, but at a heightened level, which enables users to find a meaningful connection like in the real world. IMVU envisions a world of deepening friendships through highly connective virtual shared experiences. Recent studies have shown that loneliness is on the rise and the lack of strong social connection is now considered a determinant of overall health and wellness. The strengthened executive team will help accelerate product innovation, support continued mobile growth, and continue to build the world's largest avatar-based social network. REDWOOD CITY, Calif., /PRNewswire/ - IMVU, the leading avatar-based social network today announces that it expanded its executive team by hiring Daren Tsui as the chief executive officer (CEO), Lauren Bigelow as the chief product officer, Victor Zaud as the senior vice president of marketing, John Burris as the chief development officer, and Lomit Patel as the vice president of growth. ![]() Once they see a tip and tell they tend to understand that they are being monitored and that the freight IS in fact fragile! All this, along with the service of upsizing the pallet to help minimize the risk of damage are strongly recommended if your shipping your game any significant distance. This is also a huge sign for the carriers to handle with care when they see these indicators on the freight. This assures you and us that the freight during transit has remained upright and has not fallen over. Last, EVERY GAME gets a tip and tell affixed to the shipment. You can stamp, write and scream DO NOT STACK all over the freight and paperwork but guess what they will do? Stack on top of it to get more pallets on the truck. The old saying "you get what you pay for" can not be stressed enough in LTL shipping! For the cost of this high end equipment, don't skimp on the shipping! Trust us on these, we have learned the hard way! Some of these carriers are paid by the skid. It's minimal in retrospect of what these games can cost, not to mention replacing a pristine fully restored original game or even a brand new game that is no longer in production! We will ONLY use an above average rated carrier to transport your game. Years ago as a company we made the decision to stay off them. The not so great, yeah there cheap but they have extremely high claims for damaged freight. We have used them all over the past 25 years. There are some great carriers and not so great carriers out there. The last piece if vital info you should know about is the actual carrier. This service including the 40X48 pallet is normally $45 but we are now offering this service at NO CHARGE! ![]() One thing is certain though, if it's not strapped in and it's on a 40X48 pallet it's much harder to tip over! This pallet upsizing service does change the freight cost because it puts it into the next freight class category due to its larger footprint. We have no idea as it goes from terminal to terminal and truck to truck. Does it stay that way from truck to truck? We would hope so, but honestly once it leaves our dock it is no longer under our control. Once that game gets loaded on the trailer at our dock it is mandatory that we have the driver strap that game in. A 31X31 can tip over quite easily if the truck hits a curb and it is not strapped in to the wall of the trailer. A pinball machine on a 40X48 pallet is much more planted and creates a larger footprint. The other thing it greatly increases is the inability for the freight to tip over. Transferring the game over to a standard 40X48 pallet allows more space around your game to help minimize the risk of other freight or forklift drivers damaging it. Why does this matter? Well, this means the various other freight traveling with your game can hit your game since the pallet and the games box are the same size. This means the size of the pallet is the same size of the box. Pinball manufactures use a 31X31 pallet so they can get 3 wide in semi trucks and/or containers heading overseas. The second part of this equation is the pallet size. Although damage is rare, it happens! If it happens we handle every single aspect of this process AND we alsoy the deductible for you! We have used this policy multiple times and it is a much much smoother process than trying to deal with the carrier. Our 3rd party policy only adds $40 to your quote. NEW OR USED no matter what you paid for it! This includes the specialized "White Glove" carriers. Most EVERY SINGLE freight carrier ONLY covers $1500.00 on coin operated pinball machines and arcade games. ![]() That category is covered based on the commodity. (Well they can, but that is also LTL just a different division than your local driver in the small trucks) So what all this means is when freight goes LTL it is put into into a freight class category. Why is this important? Well, because arcade games go on LTL (Less Than Truckload) semi truck freight carriers when traveling long distances. WE NOW OFFER INCLUDE A 3RD PARTY INSURANCE POLICY & PALLET UP-SIZE ON ALL GAMES SHIPPED! WE ONLY SHIP ON TOP RATED CARRIERS! This is the single most important paragraph you will read on this or any other arcade game/pinball website: Why buy from us? We'll just let our customers tell you why. Sometimes we have to update this link, so if no workie, just GOOGLE US AND CHECK OUR REVIEWS! ALL 5 STARS! We know there's a lot of reading but it'll be worth it if you're new to this Hobby! If you're new to pinball, some of the information below will be very helpful for you. For USED Pinball Machine & Arcade Game Inventory please scroll down to here, but before you do, the information below on shipping is VERY important. ![]() Triangle® credit cards are issued by Canadian Tire Bank. *The Triangle Rewards Program is owned and operated by Canadian Tire Corporation, Limited. Our Lowest Prices of the Year are defined as the period between January 1 to December 31, 2022. ✛ased on the promotion prices as advertised in accordance with this flyer's sale dates. Visit Online Ordering for more information. Bulk items will only be delivered within a 100km radius of the Store. Shipping fees and delivery times vary depending on location, size and weight of the item(s) and is only available within the province of the Canadian Tire retail location (“Store”) from which the item(s) was purchased. We reserve the right to limit quantities. Items may be display models or not exactly as shown and may not be available in all stores. ◊Pricing, selection, and availability of store clearance items are determined by each store. ®/TMSport Chek is a registered trademark of FGL Sports Ltd, used under licence. ![]() ®/TMMark’s is a registered trademark of Mark’s Work Warehouse Ltd, used under licence. Visit Triangle Rewards: Sign Up & Earn Today for more information. Bonus CT Money collected from online orders will be applied to the member’s Triangle Rewards™ account within 5 weeks of the purchase date. The offered rate is exclusive of any bonus or promotional offers or redemption transactions. Not all items sold at Canadian Tire earn CT Money. Any bonus multiplier is based on the base rate of collecting CT Money. You cannot collect paper Canadian Tire Money on bonus offers. † In the form of electronic Canadian Tire Money® (CT Money®). Examples of borrowing costs (rounded to the nearest cent) assuming that all charges are purchases bearing interest at the regular annual rate of 20.99%, a 30 day month, no charges made on special payment plans and no other fees, additional payments or other changes are: The Triangle Mastercard and the Triangle World Elite Mastercard do not have an annual fee. The billing period covered by each statement can be from 28-33 days. For residents of Quebec, the period between the statement date and the due date for payment is 26 days. The minimum payment is the sum of (a) the greater of: (i) interest and fees shown on your statement + $10 or (ii) 5% of the New Balance, excluding amounts on special payment plans, (b) any balance over your credit limit, (c) any amounts past due not included in (b) above, and (d) the amount of any equal payments plan instalments then due. Some applicants may receive a higher or lower regular annual rate depending on a credit evaluation. Offer subject to change without notice.Īdditional information for residents of Quebec only: The regular annual rate for persons applying for the Triangle Mastercard and the Triangle World Elite Mastercard is 22.99% for cash transactions and related fees and 20.99% for all other charges. Any unpaid portion not received by the due date will no longer form part of the equal payments plan and interest will accrue on that amount from the day after the date of your next statement at the applicable regular annual rate. Each month during an equal payments plan you are required to pay in full by the due date that month’s equal payments plan instalment. There is no administration fee charged for entering into a special payments plan. However, if we do not receive the full minimum due on a statement within 59 days of the date of that statement, or any event of default (other than a payment default) occurs under your Cardmember Agreement, all special payment plans on your account will terminate and (i) you will then be charged interest on the balances outstanding on such plans at the applicable regular annual rate from the day after the date of your next statement, and (ii) the balances outstanding will form part of the balance due on that statement. Interest does not accrue during the period of the plan. Dealers may sell for less.įinancing available is “Equal payments, no interest” for 24 months (unless otherwise stated) and is only available on request, on approved credit and on purchases of $150 (unless otherwise stated) or more (Gift Cards excluded) made with your Triangle credit card at Canadian Tire, Sport Chek, Mark’s, L’Équipeur, Atmosphere, Sports Rousseau, Hockey Experts, L’Entrepôt du Hockey and participating Sports Experts. ![]() **Online prices and sale effective dates may differ from those in-store and may vary by region. ![]() ±Was price reflects the last national regular price this product was sold for. The tire producer / manufacturer and Canadian Tire uses this fee to pay for the collection, transportation, and processing of used tires.ĬANADIAN TIRE® and the CANADIAN TIRE T riangle Design are registered trade-marks of Canadian Tire Corporation, Limited. △The tire producer / manufacturer of the tires you are buying, and Canadian Tire is responsible for the recycling fee that is included in your invoice. At Tablao Flamenco la Carmela, we offer a unique show in the world, full of surprises, an interactive show full of dynamism. Flamenco show at Tablao la Carmela, Puerta del Sol, Madrid. Master among masters, He began in the Neptuno hall. These are dance shows always accompanied by vocals and guitar. A Flamenco Fusion show directed by the master Juan Andrés Heredia Maya. This unique experience can be made even better by savouring a succulent dinner or enjoying a long drink. The city of Madrid has excellent flamenco shows. Enjoy the music of legends such as Paco de Lucía, Sabicas, Niño Miguel and Manuel de Falla played by this unique artist, accompanied by special guests, in one of the most enchanting cities in the world. Shows and leading artists In Madrid, it is possible to enjoy the flamenco art any day of the week with shows in theatres and flamenco houses, as well as in small song and dance establishments. One of the most praised flamenco guitarists of the last decades, Pedro Javier González presents his new show as one of the highlights of the festival Maestros de Guitarra. ![]() ![]() Pedro Javier González & Dance: A glimpse of the most wonderful flamenco in the heart of Barcelona. /rebates/&.com252fAttractions-g187514-Activities-c20-t109-Madrid. These small clubs, called tablaos, have acted as. José Manuel Álvarez and Carolina Morgado, Spanish dance MADRID They’re often in darkened, cavelike spaces, with a stage nestled among patrons’ tables and chairs. Feel the passion of Barcelona Guitar Trio & Dance as you listen to some of the greatest compositions brought to you by names such as Manuel de Falla, Federico García Lorca, Chick Corea and Paco de Lucía itself in the Palau de la Música Catalana, one of the most beautiful concert halls in the world and a beacon of the Catalan modernist architecture. ![]() Las Carboneras A unique flamenco show combined with a tour of the country’s best regional food. Tablao Flamenco Torero Enjoy flamenco in its purest state at this small venue in the heart of Madrid. Under the artistic management of two leading flamenco figures, the dancer, Úrsula Moreno, and the guitarist, Antonio Andrade. Three internationally renowned guitarists, the maestros Manuel González, Xavier Coll and Luis Robisco combine with one of the most exciting pairs of dancers in the country to deliver an unforgettable tribute to Paco de Lucía, fusing both flamenco and Spanish guitars. El Lucero Flamenco and dance school that offers flamenco shows every Saturday, very close to Paseo del Prado. Maestros de la Guitarra present two shows in the Palau de la Música Catalana in Barcelona:īarcelona Guitar Trio & Dance: An unforgettable tribute to Paco de Lucía. ![]() Kay has a blaster with a few settings, which we briefly see in action here - one is used to stun a guard with a shield - while Nix can be sent scampering off again to pick up a heavier weapon any enemy's dropped during battle, for Kay to briefly use before dropping. Then we get discovered and it's into some gunplay. That sets a big crate moving over the hangar, which we can quietly climb onto to progress out of sight. From here we stealth around the sides of a hanger to find a few more guards, and send Nix to quietly push a button activating a nearby crane. Watch on YouTube Here's the gameplay walkthrough in full for Star Wars: Outlaws from the Ubisoft Forward conference.įluid transitions were the running theme from the walkthrough, which opened with a classic Naughty Dog-style seamless switch from cutscene - featuring Nix, Kay's pet-slash-friend, stealing a kind of space avocado from a table - into Kay clonking a guard over the head to knock him out. ![]() ![]() ![]() That's the kind of thing where they were so excited to work with us." As he put it, "being able to tell the story of an emerging scoundrel through the spectrum of an open world, being able to go to a cantina to hang out with Imperials and criminal syndicates, being able to venture out into the open world and get onto your speeder and get into chases, do jumps all that stuff, and then hop into your spaceship with ND-5 and blast into the galaxy, hit hyperspace whenever you want. It's that open world fantasy - and in particular the type of fluid transitions we saw with them demo - that Khavari says is what got Lucasfilm hooked on the idea. Lucasfilm was so excited to jump in and talk about it from that angle." This is building world stories, having a hero's journey, and a protagonist navigating through that open world. "It was really, when we landed on that scoundrel fantasy, and then when we talked to them about that era, it was really just about seeing that - especially Massive, as 'experts of open world', this is the bread and butter. When asked if that was something Lucasfilm Games or Disney were specifically after, he said quite simply, "No - definitely not." Between Rogue One, Solo, and now Andor there have been a few stories about heists and scoundrels and criminal underworlds in Disney's world of Star Wars, but most of all it's a remarkably similar setup to that of Project Ragtag, the game Amy Hennig was working on for EA's Visceral, before it was infamously cancelled in 2017.Īccording to Khavari, that's pure coincidence. Availability: Out 2024 on PS5, Xbox Series X/S, and PC.The basic setup, we're told, is Kay comes out on the bad side of a job gone wrong, and has to worm her way out of trouble through grinding credits for the gangs of the underworld and attempting to pull off "one of the greatest heists the galaxy has ever seen." But we've also had a bit of extra time with it behind closed doors out in Los Angeles this week, where we saw the new extended walkthrough of a mission ahead of time and spoke with Navid Khavari, Outlaws' narrative director, and game director Mathias Karlson, who talked us through it in a bit more detail.Īs you've likely already seen, Outlaws is an "open-world, single-player action adventure game" set in the year between The Empire Strikes Back and Return of the Jedi - specifically in the aftermath of the battle for Hoth. Ubisoft gave us a proper look at Star Wars: Outlaws at its big Ubisoft Forward conference today, showing its latest wise-cracking scoundrel Kay Vess in action. |